RT journal article T1 Wafer-Scale Two-Dimensional Semiconductors for Deep UV Sensing A1 Shiffa, Mustaqeem A1 Dewes, Benjamin T. A1 Bradford, Jonathan A1 Cottam, Nathan D. A1 Cheng, Tin S. A1 Mellor, Christopher J. A1 Makarovskiy, Oleg A1 Rahman, Kazi A1 O'Shea, James N. A1 Beton, Peter H. A1 Novikov, Sergei V. A1 Ben Fernández, Teresa A1 González Robledo, David A1 Xie, Jiahao A1 Zhang, Lijun A1 Patanè, Amalia A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica K1 gallium selenide K1 molecular beam epitaxy K1 optoelectronics K1 photodetectors AB 2D semiconductors (2SEM) can transform many sectors, from information and communication technology to healthcare. To date, top-down approaches to their fabrication, such as exfoliation of bulk crystals by “scotch-tape,” are widely used, but have limited prospects for precise engineering of functionalities and scalability. Here, a bottom-up technique based on epitaxy is used to demonstrate high-quality, wafer-scale 2SEM based on the wide band gap gallium selenide (GaSe) compound. GaSe layers of well-defined thickness are developed using a bespoke facility for the epitaxial growth and in situ studies of 2SEM. The dominant centrosymmetry and stacking of the individual van der Waals layers are verified by theory and experiment; their optical anisotropy and resonant absorption in the UV spectrum are exploited for photon sensing in the technological UV-C spectral range, offering a scalable route to deep-UV optoelectronics. PB John Wiley and Sons Inc SN 1613-6829 YR 2024 FD 2024 LK http://hdl.handle.net/10498/32125 UL http://hdl.handle.net/10498/32125 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 13-nov-2026