RT journal article
T1 Optimization of a carbon adsorption/HS-GC–MS method for ignitable liquids classification from fire debris
A1 Asor Misolas, A.
A1 Ferreiro González, Marta
A1 Palma Lovillo, Miguel
A2 Química Analítica
K1 Fire debris
K1 Ignitable liquids
K1 Total ion spectrum
K1 Principal component analysis
AB The main goal of any fire investigation is to find the origin and cause of fire. Fire is commonly initiated or accelerated by using ignitable liquids (ILs). The analysis of fire debris can contribute to the determination of the origin of the fire. In this study, the thermal desorption of IL residues (ILRs) from activated charcoal strips (ACS) was optimized prior to headspace- gas chromatography- mass spectrometry (HS-GC–MS) analysis for the identification and classification of ILRs in fire debris samples. A Box-Behnken Design (BBD) coupled with Response Surface Methodology (RSM) were used to determine the optimized conditions in the following ranges: incubation temperature (80–140 ˚C), incubation time (30–60 min), and agitation speed (250–750 rpm). The sum of the differences between the total ion spectrum (TIS) of gasoline and diesel was used as dependent variables. The quadratic model was significant with a p- value of 0.0061 and a coefficient of determination equals to 0.911. RSM revealed that an increase in incubation temperature and agitation speed increases the response. The optimized conditions were 140 ◦ C and 750 rpm. Further optimization of the incubation time was studied by analyzing fire debris samples at different times (5–30 min) and 5 min was determined as the optimum condition. The final optimized conditions were applied in combination with chemometrics for the characterization of fire debris samples burned with different ILs. The obtained results demonstrate the feasibility of the method in fire debris analysis which avoids the use of organic solvents providing a greener and faster alternative method.
PB ELSEVIER
SN 0026-265X
YR 2024
FD 2024-03-08
LK http://hdl.handle.net/10498/32839
UL http://hdl.handle.net/10498/32839
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 12-nov-2026