RT journal article T1 Dilute acid pre-treatment of rapeseed straw for fermentable sugar generation A1 Castro, Eulogio A1 Díaz Villanueva, Manuel Jesús A1 Cara-Corpas, Cristobal A1 Ruiz-Ramos, Encarnación A1 Romero-Pulido, Inmaculada A1 Moya, Manuel K1 Agricultural residues K1 Dilute acid pretreatment K1 Enzymatic hydrolysis K1 Rapeseed straw AB The influence of the main pretreatment variables on fermentable sugar generation from rapeseed straw is studied using an experimental design approach. Low and high levels for pretreatment temperature(140–200 ºC), process time (0–20 min) and concentration of sulfuric acid (0.5–2% w/v) were selectedaccording to previous results. Glucose and xylose composition, as well as sugar degradation, were monitored and adjusted to a quadratic model. Non-sugar components of the hydrolysates were also determined. Enzymatic hydrolysis yields were used for assessing pretreatment performance. Optimization based on the mathematical model show that total conversion of cellulose from pretreated solids can be achieved at pretreatment conditions of 200 ºC for 27 min and 0.40% free acid concentration. If optimization criteria were based on maximization of hemicellulosic sugars recovery in the hydrolysate along with cellulose preservation in the pretreated solids, milder pretreatment conditions of 144 ºC, 6 min and 2% free acid concentration should be used. PB Elsevier SN 0960-8524 YR 2011 FD 2011 LK http://hdl.handle.net/10498/33304 UL http://hdl.handle.net/10498/33304 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 04-nov-2026