RT journal article T1 Origin of reduced magnetization and domain formation in small magnetite nanoparticles A1 Nedelkoski, Zlatko A1 Kepaptsoglou, Demie A1 Lari, Leonardo A1 Wen, Tianlong A1 Booth, Ryan A. A1 Oberdick, Samuel D. A1 Galindo Riaño, Pedro Luis A1 Ramasse, Quentin M. A1 Evans, Richard F. L. A1 Majetich, Sara A1 Lazarov, Vlado K. A2 Ingeniería Informática AB The structural, chemical, and magnetic properties of magnetite nanoparticles are compared. Aberration corrected scanning transmission electron microscopy reveals the prevalence of antiphase boundaries in nanoparticles that have significantly reduced magnetization, relative to the bulk. Atomistic magnetic modelling of nanoparticles with and without these defects reveals the origin of the reduced moment. Strong antiferromagnetic interactions across antiphase boundaries support multiple magnetic domains even in particles as small as 12-14 nm. PB Nature Publishing Group SN 2045-2322 YR 2017 FD 2017 LK http://hdl.handle.net/10498/33936 UL http://hdl.handle.net/10498/33936 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 11-nov-2026