RT journal article
T1 Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization
A1 Sokolov, Maxim N.
A1 Anyushin, Alexander V.
A1 Hernández Molina, Rita
A1 Llusar, Rosa
A1 García Basallote, Manuel
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
K1 ICPC-21
AB This contribution is a documentation of recent advances in the chemistry of chalcogenide polynucleartransition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxogroups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influenceof the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolationand structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordinationto Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.
PB Walter de Gruyter GmbH
SN 1365-3075
YR 2017
FD 2017
LK http://hdl.handle.net/10498/34022
UL http://hdl.handle.net/10498/34022
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 10-nov-2026