RT journal article
T1 Hot Electron Collection on Brookite Nanorods Lateral Facets for Plasmon-Enhanced Water Oxidation
A1 Naldoni, Alberto
A1 Montini, Tiziano
A1 Malara, Francesco
A1 Mróz, Marta
A1 Beltram, Alessandro
A1 Virgili, Teresilla
A1 Boldrini, Clara
A1 Marelli, Marcello
A1 Romero Ocaña, Ismael
A1 Delgado Jaén, Juan José
A1 dal Santo, Vladimiro
A1 Fornasiero, Paolo
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
K1 titanium dioxide
K1 shape controlled
K1 surface plasmons
K1 selective oxidations
K1 hydrogen peroxide
AB hotocatalytic reactions could enhance the share of chemicals produced through renewable sources. The efficiency of photocatalysts drastically depends on light absorption, on the surface energy of the crystals, and on the properties of the nanobuilding blocks assembled in devices. Here, we show that photoelectrochemical water oxidation on brookite TiO2 nanorods is greatly enhanced by engineering the location of Au nanoparticles deposition. Brookite photoanodes show a very low onset potential for water oxidation to H2O2 of −0.2 VRHE due to energetics of exposed crystal facets. By combining electrochemical measurements and ultrafast optical spectroscopy, we link the water oxidation activity with electron–hole recombination phenomena. The preferential Au decoration at the electrode/water interface produces highly enhanced photocurrent, while when Au is distributed along the whole film thickness, the activity is depressed with respect to pure brookite. In the latter case, Au nanoparticles act as recombination centers with plasmonic carriers recombining on the same time scale of their generation (fs). Conversely, Au surface decoration enables a hot electrons lifetime 4 orders of magnitude longer (ns) due to efficient hopping on brookite lateral facets, thus providing an efficient path for plasmon-enhanced solar water oxidation.
PB ACS Publications
SN 2155-5435
YR 2016
FD 2016-12-28
LK http://hdl.handle.net/10498/35942
UL http://hdl.handle.net/10498/35942
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 21-sep-2026