RT journal article T1 Review and novel formulae for transmittance and reflectance of wedged thin films on absorbing substrates A1 Ballester, Manuel A1 Márquez Navarro, Emilio José A1 Bass, John A1 Würsch, Christoph A1 Willomitzer, Florian A1 Katsaggelos, Aggelos K. A2 Física de la Materia Condensada K1 thin solid films K1 spectrophotometry K1 transmittance K1 reflectance K1 wedge-shaped films K1 substrate absorption AB Historically, spectroscopic techniques have been essential for studying the optical properties of thin solid films. However, existing formulae for both normal transmission and reflection spectroscopy often rely on simplified theoretical assumptions, which may not accurately align with real-world conditions. For instance, it is common to assume (1) that the thin solid layers are deposited on completely transparent thick substrates and (2) that the film surface forms a specular plane with a relatively small wedge angle. While recent studies have addressed these assumptions separately, this work presents an integrated framework that eliminates both assumptions simultaneously. In addition, the current work presents a deep review of various formulae from the literature, each with their corresponding levels of complexity. Our review analysis highlights a critical trade-off between computational complexity and expression accuracy, where the newly developed formulae offer enhanced accuracy at the expense of increased computational time. Our user-friendly code, which includes several classical transmittance and reflectance formulae from the literature and our newly proposed expressions, is publicly available in both Python and Matlab at this link. PB Institute of Physics SN 1361-6501 YR 2025 FD 2025 LK http://hdl.handle.net/10498/36450 UL http://hdl.handle.net/10498/36450 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 10-may-2026