RT journal article
T1 Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism
A1 Botubol Ares, José Manuel
A1 Hanson, James R.
A1 Hernández Galán, Rosario
A1 González Collado, Isidro
A2 Química Orgánica
AB A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using tert-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed.
PB American Chemical Society
SN 2470-1343
YR 2017
FD 2017
LK http://hdl.handle.net/10498/36481
UL http://hdl.handle.net/10498/36481
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 10-nov-2026