RT conference output
T1 Development of a chemical model to predict the doses of calcium sulfate and tartaric acid to acidify musts in Sherry area
A1 Gómez, J.
A1 Palacios Santander, José María
A1 Lasanta Melero, Cristina
A1 Cubillana Aguilera, Laura
A1 Arnedo, R.
A1 Casas, J. A.
A1 Amilibia, B.
A1 LLoret, I.
A2 Ingeniería Química y Tecnología de Alimentos
A2 Química Analítica
AB Calcium sulfate is normally used as a complementary acidifier combined with tartaric acid. The doses corresponding to each one depend on the desired reduction of pH and on the composition of musts. However, considering that there are several interrelated chemical equilibria implied (tartaric acid dissociation, calcium tartrate and potassium bitartrate precipitation, etc.), it is not easy to predict the effect on pH of a mixed tartaric acid and calcium sulfate addition and to determine the necessary doses to reach the final pH required by the winemaker. In a model previously developed by the authors, the prediction of pH after an acidification was properly achieved. On the contrary, in the same model the prediction of the necessary doses of acidifiers to achieve a desired pH have higher errors due to some parameters, as pH and pK, are found as exponential functions in the equations. This work develops and verify the necessary corrections to the models so that appropriate predictions of the doses are obtained. With these corrections, prediction errors of less than 5% were obtained for all doses of acidifiers, confirming the good comprehension of the chemical equilibria involved in this practice.
PB EDP Sciences
SN 2117-4458
YR 2017
FD 2017
LK http://hdl.handle.net/10498/36616
UL http://hdl.handle.net/10498/36616
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 06-nov-2026