RT journal article
T1 Recent green approaches in liquid-phase microextraction
A1 Aguirre, Miguel Ángel
A1 Arroyo Manzanares, Natalia
A1 Carbonell Rozas, Laura
A1 Grau, José
A1 Moreno Aguilar, Carlos
A1 Vidal, Lorena
A2 Química Analítica
K1 Automation
K1 Green analytical chemistry
K1 Green sample preparation
K1 Green Solvents
K1 Liquid-Phase Microextraction
AB The miniaturization of conventional extraction techniques, particularly microextraction methods, has led to areduction in the use of hazardous reagents and waste. However, the continued use of toxic solvents and materials, along with time-consuming sample preparation processes, negatively impacts the overall sustainability ofthese methods. As a result, there is growing interest in exploring greener alternatives. This review highlights themost promising green solvents for liquid-phase microextraction, including (natural) deep eutectic solvents, lowtoxicity ionic liquids, surfactants, micellar solvents, and bio-based solvents, emphasizing their applications ininnovative sample preparation techniques in the last five years. Particular emphasis is placed on their use inautomated and semi-automated systems, in line with the increasing role of automation in Analytical Chemistry.Selected applications have been carefully reviewed and discussed to illustrate key advances in the use of greensolvents and automation for extracting a wide range of compounds from various matrices. In addition, futureperspectives are outlined to guide further development of liquid-phase microextraction in alignment with currenttrends in green sample preparation.
PB Elsevier
SN 2772-5820
YR 2025
FD 2025-07-17
LK http://hdl.handle.net/10498/37870
UL http://hdl.handle.net/10498/37870
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 09-nov-2026