RT journal article
T1 MOF-Derived PdCo and PdMn Systems as Versatile Catalysts in Alkyne Semihydrogenation
A1 Martínez, Jordán Santiago
A1 Carpisassi, Luigi
A1 Egea, Gonzalo
A1 Mazarío, Jaime
A1 Wittee Lopes, Christian
A1 Mora Moreno, Carmen
A1 Trasobares Llorente, Susana
A1 Vaccaro, Luigi
A1 Calvino Gámez, José Juan
A1 Agostini, Giovanni
A1 Oña Burgos, Pascual
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
K1 alkyne semihydrogenation
K1 bimetallic nanoparticles
K1 heterogeneous catalysis
K1 MOF-derived
K1 nanomaterials characterization
AB This study investigates the structure and catalytic properties of bimetallic nanocomposites derived from PdCo- and PdMn-based metal-organic frameworks. These materials, synthesized via chemical (Q) and thermal treatments (T), resulted in PdCo-QT and PdMn-QT catalysts containing Pd-based nanoparticles modified with Co or Mn and supported on N-doped carbon. Detailed characterization techniques confirm these complex structures, including high-resolution transmission electron microscopy, scanning transmission electron microscopy energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy. The catalytic performances of these materials were evaluated for the selective semihydrogenation of phenylacetylene and 4-octyne under soft conditions (1 H2 bar, room temperature) in batch reactors, demonstrating very high selectivity (≥95 mol %) toward alkenes at high conversion levels (≥94 mol %). Moreover, they displayed significant stability after five catalytic cycles with minimal leaching and highly competitive values of alkyne productivity in the semihydrogenation of phenylacetylene. The study also explored the potential of these catalysts in continuous gas-phase reactions, where PdCo-QT demonstrated remarkable catalytic activity and selectivity with a high gas hourly space velocity.
PB American Chemical Society
SN 2155-5435
YR 2025
FD 2025
LK http://hdl.handle.net/10498/37931
UL http://hdl.handle.net/10498/37931
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 11-nov-2026