RT journal article T1 Semi-empirical model for Impurity-to-Band energy reduction in semiconducting boron-doped diamond A1 Alba Muñoz, Gonzalo A1 Araújo Gay, Daniel A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica A2 Ingeniería en AutomáticaElectrónica, Arquitectura y Redes de Computadores K1 boron doped diamond K1 semiconducting diamond K1 activation energy K1 diamond for electronics AB A semi-empirical analytical model which describes the reduction of impurity-to-band activation energy in boron-doped diamond, induced by doping and compensation levels. The model’s foundation mainly lies in the broadening of the impurity band. Crucially, compensation is integrated into this framework as a key multifaceted variable accounting for electrostatic disorder and impurity band occupancy. A two-stage optimization methodology is used for the comparative analysis with available experimental data. This model serves as a robust predictive framework for the electrical characterization and design of diamond-based semiconductor devices. The model’s predictions align closely with literature data, significantly outperforming previous theoretical frameworks by capturing the influence of compensation across the entire doping range. PB Elsevier SN 0925-9635 YR 2026 FD 2026-04-13 LK http://hdl.handle.net/10498/39421 UL http://hdl.handle.net/10498/39421 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 08-nov-2026