RT journal article
T1 Synthesis of the new water soluble vinyl ruthenium complex [RuCp(=C=CPh)(PPh3)(mPTA2](CF3SO3) (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane): chemical reactivity and catalytic properties for redox isomerization of allylic alcohols
A1 Ríos Hierro, Isaac de los
A1 Scalambra, Franco
A1 Jara Pérez, Vicente
A1 Romerosa, Antonio
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
K1 Ruthenium
K1 Methyl-PTA
K1 Metal vinylidene
K1 Allylic alcohols
K1 Redox isomerization
K1 Water
AB The Ruthenium(II) phenylvinylidene complex [RuCp(=C=CHPh)(mPTA)(PPh 3 )](CF 3 SO 3 ) 2 (2) has been synthesized and characterized by NMR, IR and elemental analysis and its structure by single crystal X-ray diffraction (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane). The chemical reactivity of this complex against water, acid medium, O 2 , CO, isopropylamine, cyclohexylamine, 2-aminopyridine, ethanethiol and ethanol was studied. As a result, new amino and thio-carbenes were obtained and characterized. Additionally, complex 2 was evaluated as catalyst for the isomerisation of linear allylic alcohols with different tail lengths.
PB Elsevier
SN 0277-5387
YR 2026
FD 2026-10
LK http://hdl.handle.net/10498/39558
UL http://hdl.handle.net/10498/39558
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 10-nov-2026