TY - GEN AU - Serrano-Plana, Joan AU - Aguinaco Martín, Almudena AU - Belda, Raquel AU - García-España, Enrique AU - García Basallote, Manuel AU - Company, Anna AU - Costas, Miquel A4 - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica PY - 2016 UR - http://hdl.handle.net/10498/20489 AB - The reaction of [Fe(CF3SO3)2(PyNMe3)] with excess peracetic acid at ¢40 8C leads to the accumulation of a metastable compound that exists as a pair of electromeric species, [FeIII(OOAc)(PyNMe3)]2+ and [FeV(O)(OAc)(PyNMe3)]2+, in fast equilibrium.... LA - eng PB - Willey KW - epoxidation KW - kinetics KW - nonheme iron complexes KW - olefins KW - oxidation TI - Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species DO - 10.1002/anie.201601396 ER -