TY - GEN AU - Serrano-Plana, Joan AU - N. Oloo, Williamson AU - Acosta-Rueda, Laura AU - K. Meier, Katlyn AU - Verdejo, Begoña AU - García-España, Enrique AU - García Basallote, Manuel AU - Münck, Eckard AU - Que, Lawrence Jr. AU - Company, Anna AU - Costas, Miquel A4 - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica PY - 2015 UR - http://hdl.handle.net/10498/20491 AB - An unprecedentedly reactive iron species (2) has been generated by reaction of excess peracetic acid with a mononuclear iron complex [FeII(CF3SO3)2(PyNMe3)] (1) at cryogenic temperatures, and characterized spectroscopically. Compound 2 is kinetically... LA - eng PB - ACS Publications TI - Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong CH Bonds with Stereoretention DO - 10.1021/jacs.5b09904 ER -