TY  - GEN 
AU  - Bustelo, Emilio
AU  - L. Gushchin, Artem
AU  - Fernández-Trujillo Rey, María Jesús
AU  - García Basallote, Manuel
AU  - García Algarra, Andrés
A4  - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
PY  - 2015
UR  - http://hdl.handle.net/10498/20493
AB  - Whereas the cluster [Mo3S4(acac)3(py)3]+ ([1]+, acac=acetylacetonate, py=pyridine) reacts with a variety of alkynes, the cluster [W3S4(acac)3(py)3]+ ([2]+) remains unaffected under the same conditions. The reactions of cluster
[1]+ show polyphasic...
LA  - eng
PB  - Willey
KW  - cluster compounds
KW  - cycloaddition
KW  - density functional calculations
KW  - kinetics
KW  - reaction mechanisms
TI  - On the Critical Effect of the Metal (Mo vs. W) on the [3++2] Cycloaddition Reaction of M3S4 Clusters with Alkynes: Insights from Experiment and Theory
DO  - 10.1002/chem.201502644
ER  -