TY - GEN AU - Flores-Giubi, M. Eugenia AU - Botubol Ares, José Manuel AU - Durán Peña, María Jesús AU - Escobar Montaño, Felipe AU - Zorrilla Cuenca, David AU - Sánchez Márquez, Jesús AU - Muñoz, Eduardo AU - Macías Sánchez, Antonio José AU - Hernández Galán, Rosario A4 - Química Física A4 - Química Orgánica PY - 2020 SN - 0031-9422 UR - http://hdl.handle.net/10498/24107 AB - The reaction mechanism of the intramolecular [2 + 2] cycloaddition from a jatrophane precursor to the gaditanane skeleton, an unprecedented 5/6/4/6-fused tetracyclic ring framework recently isolated from Euphorbia spp., was studied using the bond... LA - eng PB - PERGAMON-ELSEVIER SCIENCE LTD KW - Euphorbia gaditana Coss KW - Euphorbiaceae KW - Biosynthesis KW - Diterpene KW - Jatrophane KW - Gaditanane KW - [2+2] cycloaddition TI - Bond reactivity indices approach analysis of the [2+2] cycloaddition of jatrophane skeleton diterpenoids from Euphorbia gaditana Coss to tetracyclic gaditanone DO - 10.1016/j.phytochem.2020.112519 ER -