TY  - GEN 
AU  - Ballesteros-Soberanas, Jordi
AU  - Hernández Garrido, Juan Carlos
AU  - Cerón-Carrasco, José Pedro
AU  - Leyva-Pérez, Antonio
A4  - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
PY  - 2022
SN  - 1090-2694
UR  - http://hdl.handle.net/10498/27230
AB  - The de-novo synthesis of soluble or solid-supported Pd-(CaCO3)(n) clusters (n = 2-13) and their high catalytic activity for the semi-hydrogenation of internal alkynes compared to terminal alkynes, is presented. Mechanistic studies show that this...
LA  - eng
PB  - ELSEVIER
KW  - Metal clusters
KW  - Minimum catalytic unit
KW  - Semi-hydrogenation of alkynes
KW  - Lindlar catalyst
KW  - Internal alkynes
TI  - Selective semi-hydrogenation of internal alkynes catalyzed by Pd-CaCO3 clusters
DO  - 10.1016/J.JCAT.2022.02.020
ER  -