TY - GEN AU - Dantignana, Valeria AU - Pérez Segura, María del Carmen AU - Besalú Sala, Pau AU - Delgado Pinar, Estefanía AU - Martínez Camarena, Álvaro AU - Serrano Plana, Joan AU - Álvarez Núñez, Andrea AU - Castillo González, Carmen Esther AU - García España, Enrique AU - Luis, Josep M. AU - García Basallote, Manuel AU - Costas, Miquel A4 - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica PY - 2022 SN - 1433-7851 UR - http://hdl.handle.net/10498/29360 AB - Two oxoiron(IV) isomers (R2a and R2b) of general formula [FeIV(O)(RPyNMe3)(CH3CN)]2+ are obtained by reaction of their iron(II) precursor with NBu4IO4. The two isomers differ in the position of the oxo ligand, cis and trans to the pyridine donor. The... LA - eng PB - Wiley KW - Atom Transfer KW - Iron KW - Isomerization KW - Oxidation KW - Oxoiron TI - Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity DO - 10.1002/anie.202211361 ER -