TY  - GEN 
AU  - Gutiérrez Blanco, María
AU  - García Algarra, Andrés
AU  - Guillamón, Eva
AU  - Fernández-Trujillo Rey, María Jesús
AU  - Oliva, Mónica
AU  - García Basallote, Manuel
AU  - Llusar, Rosa
AU  - S. Safont, Vicent
A4  - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
PY  - 2024
SN  - 1520-510X
UR  - http://hdl.handle.net/10498/31135
AB  - Semihydrogenation of internal alkynes catalyzed by the air-stable imidazolyl amino [Mo3S4Cl3(ImNH2)3]+ cluster selectively affords the (Z)-alkene under soft conditions in excellent yields. Experimental results suggest a sulfur-based mechanism with the...
LA  - eng
PB  - AMER CHEMICAL SOC
TI  - Spin-Crossing in the (Z)‑Selective Alkyne Semihydrogenation Mechanism Catalyzed by Mo3S4 Clusters: A Density Functional Theory Exploration
DO  - 10.1021/ACS.INORGCHEM.3C03057
ER  -