TY - GEN AU - García Algarra, Andrés AU - Fernández-Trujillo Rey, María Jesús AU - Hernández Molina, Rita AU - García Basallote, Manuel A4 - Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica PY - 2011 SN - 1477-9234 UR - http://hdl.handle.net/10498/39693 AB - The kinetics of reaction between the [Mo3M´S4(H2O)10]4+ clusters (M´ = Pd, Ni) and H3PO3 has been studied in 4.0 M Hpts/Lipts (pts- = p-toluenesulfonate). For both complexes there is an initial kinetic step with small absorbance changes that... LA - eng PB - The Royal Society of Chemistry KW - Kinetics KW - Cluster KW - DFT KW - Phosphorous acids TI - Kinetic, DFT and TD-DFT studies on the mechanism of stabilization of pyramidal H3PO3 at the [Mo3M´S4(H2O)10]4+ clusters (M´ = Pd, Ni) DO - 10.1039/c1dt10625b ER -