Allylic Oxidation of Alkenes Catalyzed by a Copper−Aluminum Mixed Oxide

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Allylic Oxidation of Alkenes Catalyzed by a Copper−Aluminum Mixed Oxide

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Title: Allylic Oxidation of Alkenes Catalyzed by a Copper−Aluminum Mixed Oxide
Author: García-Cabeza, Ana Leticia; Marín-Barrios, Rubén; Moreno-Dorado, F. Javier; Guerra, Francisco M.; Ortega Aguera, María Jesús; Martínez Massanet, Guillermo
Departments: Química Orgánica
xmlui.dri2xhtml.METS-1.0.item-source: Organic Letters 2014, 16, 1598−1601
Abstract: A strategy for the allylic oxidation of cyclic alkenes with a copper−aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When L-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.
Subject: allylic oxidation
Handle: http://hdl.handle.net/10498/20368
Date: 2014-03

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